化学学院有机化学研究团队陈俊屹在英国皇家化学会学术期刊Chemical Communications上发表论文“The effective taste masking of alkaloids by a water-soluble terphen[3]arene”，该项研究实现了对苦味药效分子的掩味及胃肠道可控释放。                                               随着人民生活水平的不断提高，对临床治疗药物的顺应性愈发重视，其中口感问题尤为突出。苦味因持续时间长、感知阈低等特征被视为最厌恶的味...

化学学院王超教授在《Cell Reports Physical Science》上发表论文“Regioselective nickel-catalyzed dicarbofunctionalization of unactivated alkenes enabled by picolinamide auxiliary”，该文章首次报道了镍(II)催化的吡啶酰胺导向的高烯丙基胺类衍生物的2,1-双芳基化和芳基烷基化反应（图1.）。图1. 镍催化吡啶酰胺（PA）导向的高烯丙基胺的双碳官能团化由于镍催化剂廉价易得和优异的反应性质，引起了科学家的广泛关注。...

开发低成本的高能量密度锂离子电池一直是能源化学领域的重点与难题。其中，正极材料是关键瓶颈。近年来，随着晶格氧参与氧化还原反应概念的提出，富锂材料因其高容量受到前所未有的关注。富锂材料中“富锂”结构（锂占据过渡金属层，最典型的为Li2MnO3）通常被认为是导致晶格氧参与可逆氧化还原反应的原因。本文对这一传统观点提出了不同看法。论文通过代克化老师等人提出的定量分析过渡金属与氧氧化还原的先进技术（Joule2019,...

Supramoleculartrap for catching polyamines in cells as an anti-tumor strategy Junyi Chen1,2, Hanzhi Ni2,3, Zhao Meng2,Jing Wang2, Xiayang Huang3, Yansheng Dong2,Chao Sun2,Yadan Zhang2, Lei Cui3, Jian Li3,Xueshun Jia1,3, Qingbin Meng2, Chunju Li1,3,4(李春举) 1Collegeof Environmental and Chemical Engineering, Shanghai University, Shanghai200444, P. R. China2StateKey Laboratory o...

EfficientSeparation of cis-and trans-1,2-DichloroetheneIsomers by AdaptiveBiphen[3]areneCrystals Yiliang Wang+,a Kaidi Xu+,a,bBin Li,a,b Lei Cui,a Jian Li,a Xueshun Jia,aHongbin Zhao,a Jianhui Fang,a and Chunju Li(李春举)*a,b aSchoolof Materials Science and Engineering, Center for Supra-molecular Chemistry andCatalysis and Department of Chemistry Shanghai University, Shanghai 200...

Terphen[n]arenesand Quaterphen[n]arenes (n = 3–6): One-Pot Synthesis, Self-Assembly intoSupramolecular Gels, and Iodine Capture Bin Li,a Bin Wang,b Xiayang Huang,aLu Dai,a Lei Cui,a Jian Li,a Xueshun Jia,aand Chunju Li(李春举)*a,b aCenterfor Supramolecular Chemistry and Catalysis, Department of Chemistry, ShanghaiUniversity, Shanghai 200444 (P. R. China)bCollegeof Chemistry, K...

Rhodium-Catalyzed C−H Functionalization of N-(2-Pyrimidyl)indole with Internal Alkynes: Formation of Unexpected Products by Regulating the Amount of Silver Acetate Tongyu Li, Zhuo Wang, Chen Chen*(陈晨) and Bolin Zhu*(朱柏林) Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chem...