朱柏林,博士、教授、副院长(hxxyzbl@tjnu.edu.cn)。1999年于天津南开大学获得学士学位,2004年于天津南开大学获得理学博士学位。随后赴美国加州大学伯克利分校(UC-Berkeley),美国爱荷华大学埃姆斯实验室(Ames Laboratory, ISU),和美国威斯康辛大学麦迪逊分校(UW-Madison)进行了5年的博士后研究,2009年回国到天津师范大学化学学院任教至今。
研究方向在有机合成方法学和金属有机化学等方面。主持国家自然科学基金面上项目、青年项目,天津市自然科学基金面上项目、天津市高校“中青年骨干创新人才培养计划”等科研项目。在J. Am. Chem. Soc., Chem. Commun., Org. Lett.和Organometallics等国际学术期刊上发表论文80余篇。入选天津市高校“中青年骨干创新人才培养计划”和天津市“131”创新型人才培养工程第二层次人选。
教学工作
本科生课程:《有机化学》、《有机化学实验》等
研究课题
1、过渡金属Rh、Ru等化合物催化含氮化合物直接C–H键官能化反应。
2、环戊二烯基过渡金属(Rh, Ir, Ru等)化合物的合成、结构、性质和催化应用。
部分科研项目
1、环戊二烯基双核过渡金属化合物催化的惰性键活化,国家自然科学基金面上项目,负责人,结题。
2、过渡金属配合物的互变异构:新型的太阳热能存储方式,天津市科委一般项目,负责人,结题。
3、双核金属配合物“协同”活化惰性C–H键,国家自然科学基金青年基金,负责人,结题。
部分发表文章
1. Haifang Meng, Fang Yang, Mengjia Chen, Chen Chen* and Bolin Zhu*, Rh(III)-catalyzed switchable C–H monoalkenylation and dialkenylation of 2-(1H-pyrazol-1-yl)pyridine with alkenes via rollover cyclometalation, Organic Chemistry Frontiers, 2021, 8, 773–777.
2. Chen Chen,* Yuebo Wang, Xiaonan Shi, Wan Sun, Jinghui Zhao, Yan-Ping Zhu, Liying Liu and Bolin Zhu*, Palladium-catalyzed C-2 and C-3 dual C-H functionalization of indoles: synthesis of fluorinated isocryptolepine analogues, Organic Letters, 2020, 22, 4097–4102.
3. Shaonan Wu,† Zhuo Wang,† Dianxue Ma, Chen Chen* and Bolin Zhu*, Rh(III)-catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes, Organic Chemistry Frontiers, 2020, 7, 1158–1163.
4. Shaonan Wu, Zhuo Wang, Yinwei Bao, Chen Chen,* Kun Liu* and Bolin Zhu*, A novel approach for rhodium(III)-catalyzed C-H functionalization of 2,2’-bipyridine derivatives with alkynes: a significant substituent effect, Chemical Communications, 2020, 56, 4408–4411.
5. Zhuo Wang, Tongyu Li, Jinghui Zhao, Xiaonan Shi, Dequan Jiao, Han Zheng, Chen Chen*, and Bolin Zhu*, Expeditious Synthesis of 6-Fluoroalkyl-Phenanthridines via Palladium-Catalyzed Norbornene-Mediated Dehydrogenative Annulation, Organic Letters, 2018, 20, 6640–6645.
6. Ruichen Sun, Shaowei Zhang, Xiaodan Chu, Bolin Zhu*, Synthesis, Structures, and Reactivity of Cyclometalated Complexes Formed by Insertion of Alkynes into M–C (M = Ir, Rh) Bonds, Organometallics 2017, 36, 1133–1141.
7. Bolin Zhu*, Xiaoting Hao, Yunfei Chen, Intramolecular C–H Bond Activation in Bridged Dicyclopentadienyl Dimethyl Dinuclear Complexes, Organometallics, 2014, 33, 240-248.
8. Bolin Zhu*, Xinwei Huang, Xiao-ting Hao, Synthesis and Structures of Doubly-Bridged Dicyclopentadienyl Dinuclear Rhenium Complexes, and Their Photochemical Reactions with Aromatic Halides in Benzene, Dalton Transactions, 2014, 43, 16726-16736.
9. Bolin Zhu,* Yunfei Chen, Wei Shi, Yuan Li, Xiaoting Hao, Reactions of Doubly-SiMe2-bridged Bis(cyclopentadienyl) Complexes of Molybdenum and Iron Carbonyls: Competitive Ring-to-metal Migrations of Hydrogen and SiMe2, Organometallics 2012, 31, 4046–4054.
10. Bolin Zhu,* Yuan Li, Yunfei Chen, Wei Shi, Reactions of SnMe2-Bridged Bis(cyclopentadienes) with Iron Pentacarbonyl: Migration of the SnMe2 Group, Organometallics 2012, 31, 3035–3042.